Project information
Microwave Irradiation Effect on Photochemical Reactions
- Project Identification
- GA203/02/0879
- Project Period
- 1/2002 - 12/2004
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
- Cooperating Organization
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Institute of Chemical Process Fundamentals of the ASCR, v. v. i.
- Responsible person Ing. Milan Hájek, CSc.
Microwave Irradiation Effect on Photochemical Reactions. This project represents an original idea consisting of a combination of two chemistry fields: photochemistry and microwave chemistry, creating a completely new scientific discipline microwave photochemistry. Microwaves promote two effects when applied on photochemical reactions: a generation UV radiation via electrodeless lamp and a synergic influence of MW and UV irradiation on a chemical reaction. Since the action of microwaves on photochemical reactions is essentially unknown the research will be focused on the investigation of typical photochemical reactions in the microwave field, especially from the point of view of the rate enhancement and chemical selectivity. The study will include two different kinds of MW radiation (monomode, multimode), a development of new electrodeless lamps with desired wavelength and a construction of a continuous flow photoreactor. The goal of the project is to develop a new technique for applicatio
Publications
Total number of publications: 9
2005
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The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 5: Fill Material-Dependent Emission Characteristics
Journal of Photochemistry and Photobiology A: Chemistry, year: 2005, volume: 171, edition: 1
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The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry Part 6: Photochemistry of Valerophenone and 4-Nitroanisole in High-Temperature Water
Journal of Photochemistry and Photobiology A: Chemistry, year: 2005, volume: 172, edition: 2
2004
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The electrodeless discharge lamp: a prospective tool for photochemistry. Part 5
Journal of Photochemistry and Photobiology A: Chemistry, year: 2004, volume: 171, edition: 1
2003
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Temperature Dependent Photochemical Cleavage of 2,5-Dimethylphenacyl Esters
Molecular Diversity, year: 2003, volume: 7, edition: 2-4
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The Electrodeless Discharge Lamp: A Prospective Tool for Photochemistry. Part 4: Temperature- and Envelope Material-Dependent Emission Characteristics
Journal of Photochemistry and Photobiology A: Chemistry, year: 2003, volume: 158, edition: 1
2002
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Microwave Photochemistry
Microwaves in Organic Synthesis, A. Loupy (Ed.), edition: Vyd. 1, year: 2002, number of pages: 24 s.
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Photochemistry of Alkyl Aryl Ketones on Alumina, Silica-gel and Water-Ice Surfaces
Journal of Photochemistry and Photobiology A: Chemistry, year: 2002, volume: 154, edition: 2-3
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Photolysis of Phenacyl Esters in a Two-Phase System
Synthetic Communications, year: 2002, volume: 32, edition: 16
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Temperature-sensitive photochemical aromatic substitution on 4-nitroanisole
Photochemical and Photobiological Sciences, year: 2002, volume: 1, edition: 12