Electrochemistry of closo-dodecaborate dianion and its simple exo-skeletal derivatives at carbon electrodes in aqueous phosphate buffers.

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Authors

FOJT Lukáš FOJTA Miroslav GRÜNER Bohumír VESPALEC Radim

Year of publication 2013
Type Article in Periodical
Magazine / Source Journal of Electroanalytical Chemistry
MU Faculty or unit

Central European Institute of Technology

Citation
Web http://hdl.handle.net/11104/0230431
Doi http://dx.doi.org/10.1016/j.jelechem.2013.08.016
Field Biophysics
Keywords Boron cluster; Dodecarborate; Glasy carbon electrode
Description The principle building blocks of fully synthetic boron cluster compounds are electron deficient chemical clusters, which consist only of boron and hydrogen atoms and their derivatives are characterized by exo-skeletal substituents. Unique medical promises of these compounds and their use as biomarkers cause the need for systematic investigation of their physico-chemical properties, particularly those utilizable in efficient analytical methods suitable for their characterization and determination, including electrochemical activity of the boron cluster species in water.
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