Monitoring of current-use pesticides along a Europe-Arctic transect using ships of opportunity

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Authors

BRUMOVSKÝ Miroslav KOHOUTEK Jiří LOKEN Katharina Bjarnar SÁŇKA Ondřej SORENSEN Kai NIZZETTO Luca

Year of publication 2024
Type Article in Periodical
Magazine / Source Journal of Hazardous Materials
MU Faculty or unit

Faculty of Science

Citation
web https://www.sciencedirect.com/science/article/pii/S0304389424020387?via%3Dihub
Doi http://dx.doi.org/10.1016/j.jhazmat.2024.135459
Keywords Seawater; Marine long-range transport; Monitoring; Current-use pesticides; FerryBox
Attached files
Description Understanding the occurrence and fate of current-use pesticides (CUPs) in coastal and open marine waters is essential for conducting exposure and risk assessments to ensure the protection of marine ecosystems from chemical pollution. While CUPs have been frequently studied in freshwater systems, knowledge of their behavior in marine environments remains fragmentary. This study investigated 28 CUPs across 50 sites along a transect from the Baltic outflow to pristine Arctic waters using ships of opportunity with installed FerryBox system. Overall, 14 CUPs were detected at least at one site at concentrations ranging from sub-ng/L to ng/L. CUP concentrations were higher in the Baltic outflow and decreased along the transect. Atrazine, simazine, tebuconazole, and propiconazole were detected in > 40 % of samples, including remote open sea regions, suggesting their potential for long-range marine transport. This Baltic Sea was identified as a major source of CUPs to connected marine systems. Additional CUPs were detected in the Baltic outflow, encompassing diuron, isoproturon, metazachlor, metolachlor, pyrazon, terbuthylazine, and chlortoluron. Ecotoxicological assessment indicated a moderate risk posed by metolachlor to algae. The use of the described infrastructure holds great promise for advancing our understanding of the occurrence and fate of CUPs in marine environments.
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