Regioselektivita a vliv chirální pomocné látky vázané na dipolu na enantioselektivitu 1,3-dipolární cykloadice

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Title in English	Regioselectivity and influence of chiral auxiliary bound on dipol upon enantioselectivity of 1,3-dipolar cycloaddition
Authors	TRÁVNÍČEK Martin POTÁČEK Milan
Year of publication	2001
Type	Article in Proceedings
Conference	Sborník XXV. Konference organických chemiků
MU Faculty or unit	Faculty of Science
Citation
Field	Organic chemistry
Keywords	enantioselectivity; regioselectivity; chiral auxiliary; 1;3-dipolar cycloaddition; azomethine ylides
Description	Azomethine ylides based on phenanthridinium skeleton with bound chiral auxiliary were followed in 1,3-dipolar cycloaddition with dipolarophiles. Regioselectivity and enantioselectivity in the reaction was evaluated by COSY and HMBC NMR experiments as well as by HPLC with nonracemic sorbent on detector CD Jasco.
Related projects:	Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles