Příprava nových prekurzorů titanosilikátových materiálů

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Title in English	Synthesis of new precursors to titanosilicate materials
Authors	BRLEJOVÁ Zuzana PINKAS Jiří ROESKY Herbert W.
Year of publication	2001
Type	Article in Proceedings
Conference	53. zjazd chemických spoločností, Zborník príspevkov 2.
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	titanosilicates; building units
Description	The titanosilicate molecule containg a cubic Ti4Si4O12 core was treated with a series of alcohols, silanols, phenols, and acids to replace selectively substituents on Ti and Si atoms. The results of these reactions point to a surprisingly inert Si-N bond. The substitutions take place at the isopropoxide groups on titanium. We prepared several new titanosilicate compounds by these reactions.
Related projects:	New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials