Syntéza fluorodi- a fluorotrifosforečnanů.

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Title in English	Synthesis of fluorodi- and fluorotriphosphates.
Authors	SLUKA Radek ČERNÍK Miloš
Year of publication	2000
Type	Article in Proceedings
Conference	Pokroky v anorganickej chémii. Sborník prispevkov.
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	Fluorodiphosphates; Fluorotriphosphates; Synthesis;NMR spectroscopy
Description	The possibility of synthesis of new fluorodi- and fluorotriphosphate anions was studied by 19F and 31P NMR spectroscopy. A new 1,1,2-tri-fluorodiphosphate was obtained by the substitution of chlorine in the PO2ClF(-) anion by a -OP(O)F2 group. Similarly, the so far unknown 1,1,3,3-tetrafluorotriphosphate was synthesized by the reaction of dichlorophosphate with an excess of F2P(O)OP(O)F2.
Related projects:	Crystal structures and bonding in non-metal compounds of the V., VI. , and VII. group of the periodic systém