Příprava nových metalosilikátových sloučenin

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Title in English	Synthesis of new metallosilicate compounds
Authors	BRLEJOVÁ Zuzana PINKAS Jiří KRATOCHVÍL Jan ROESKY Herbert W
Year of publication	2002
Type	Article in Proceedings
Conference	Chemické listy
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	metallosilicates; building blocks
Description	Metallosilicates find widespread application in chemical industry as catalysta, molecular sieves, and adsorbents. Molecular metallosilicates with cubic core can be prepared from silanetriols RSi(OH)3 (R = organic substituent)and alkoxides M(OR)n or chlorides RMCl3. We employed N-trimethylsilyl-N-trihydroxysilyl-2,6-diisopropylaniline and prepared a series of cubäne-like compounds [RSi(O)3MR]4 and characterized them by NMR spectroscopic methods, elemental analysis, and mass spectrometry.
Related projects:	New Nonaqueous Routes to Phosphate, Silicate, Hybrid, and Oxide Materials