Combined intra-intermolecular criss-cross cycloaddition as a efficient way to tricyclic heterocycles

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Authors

MAN Stanislav POTÁČEK Milan

Year of publication 2003
Type Article in Proceedings
Conference Euregionale 2003, Dresden, Book of Abstracts
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords combined; criss-cross; cycloadition
Description Nonsymmetrical azines undergo combined intra-intermolecular criss-cross cycloaddition with phenylisocyanates and phenylisothiocyanates. The products are ortho-peri-fused five-membered rings. The same byproducts were separated from the reaction mixture or prepared when the rections were carried out without a dipolarophile. Their structure sugested the mechanism of the reaction.
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