CHEMICAL SYNTHESES AND TECHNOLOGIES FOR THE SUSTAINABLE DEVELOPMENT I. Facile Direct alpha-Ethoxycarbonylation and alpha-Carbamoylation Reaction on Cyclic Ketones Promoted by s-l PTC and/or by Ultrasound

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Authors	PAZDERA Pavel ŠIMBERA Jan
Year of publication	2003
Type	Article in Proceedings
Conference	Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition
MU Faculty or unit	Faculty of Science
Citation
Web	http://www.mdpi.org/ecsoc-7.htm
Field	Organic chemistry
Keywords	"Green Chemistry"; SUSTAINABLE DEVELOPMENT; Nitrourea; sonochemical solid-liquid PTC; cyclic ketones
Description	Facile methods for direct ethoxycarbonylation and carbamoylation reactions on some cyclic ketones is described and discussed. A principle of this solution is an application of ultrasonic solid-liquid phase-transfer-catalysis for an enolate anion generation. Enolate anion reacts further with electrophilic reagents, i. e. with ethyl chlorocarbonate in the case of ethoxycarbonylation or nitrourea for carbamoylation reaction.
Related projects:	Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles