The synthesis and crystal structures of two-dimensional coordination polymers of Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 with praseodymium

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Authors	SPÍCHAL Zdeněk NEČAS Marek PINKAS Jiří NOVOSAD Josef
Year of publication	2004
Type	Article in Periodical
Magazine / Source	INORGANIC CHEMISTRY
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	lanthanide layered network coordination polymers
Description	Reactions of Pr(NO3)3 with Ph2P(O)-CH2CH2-P(O)Ph2 and Ph2P(O)-C5H3N-P(O)Ph2 yielded layered network coordination polymers with bidentate ligands spanning the lanthanide atoms in bridging fashion. The praseodymium cations with spacer ligands form two-dimensional building blocks assembling into either square grid or herringbone architecture.
Related projects:	Sonochemical Synthesis of Oxide and Phosphate Materials