Dichlorotetrakis(tetrahydrofuran)aluminium trichloroethylaluminate

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Authors

SLUKA Radek NEČAS Marek ŠINDELÁŘ Pavel

Year of publication 2004
Type Article in Periodical
Magazine / Source Acta Crystallographica Section E: Structure Reports Online
MU Faculty or unit

Faculty of Science

Citation
Field Inorganic chemistry
Keywords ALUMINUM TRICHLORIDE; TETRAHYDROFURAN; CRYSTAL; COMPLEXES
Description The title compound, [AlCl2(C4H8O)(4)][AlCl3(C2H5)], was prepared by the unsymmetrical cleavage reaction of the EtAlCl2 dimer with tetrahydrofuran (THF). The [AlCl2(THF)(4)](+) cation forms an approximately regular octahedron, and the [AlCl3Et](-) anion is tetrahedral.
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