Reakce trimethylsilylesterů halogenofosforečných kyselin s Lewisovými kyselinami a bazemi

Warning

This publication doesn't include Institute of Computer Science. It includes Faculty of Science. Official publication website can be found on muni.cz.

Title in English	The reactions of trimethylsilyl phosphorohalidates with Lewis acids and bases
Authors	ŽÁK Pavel ŽÁK Zdirad ČERNÍK Miloš
Year of publication	2004
Type	Article in Proceedings
Conference	Sborník 56. sjezdu chemických společností, Chemické Listy 98 (8)
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	Trimethylsilyl phosphorohalidates; Lewis acid-base reactions; donor-acceptor complexes; adducts
Description	Trimethylsilyl phosphorohalidates behave as O-donors toward strong Lewis acids and with SbCl5 and BCl3 react under formation of donor-acceptor complexes. The crystalline complexes Me3SiOPOF2(SbCl5), Me3SiOPOFCl(SbCl5), Me3SiOPOCl2(SbCl5) and (Me3SiO)2POF(SbCl5) have been isolated and structurally characterized by X-ray diffraction. The analogous adducts of BCl3 are thermally unstable and decompose to the corresponding halogenotrimethylsilane and boron phosphorohalidate. The phosphorohalidates Me3SiOPOFCl and (Me3SiO)2P2O3F2 react readily with Lewis bases pyridine and DMAP forming betaines of the fluorophosphoric acid,(B)PO2F.
Related projects:	Structure and character of bonding, properties and analysis of synthetic and natural molecular ensembles