Elektrochemicky mediované transformace benzenu, toluenu a jejich halogenovaných derivátů na Ptpc, Pt(110) a Pt(111) elektrodách

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Title in English Electrochemicallz mediated transformation of benzene, toluene and its halogenated derivates on Ptpc, Pt(110) a Pt(111) electrodes
Authors

MUSILOVÁ Natálie JANDERKA Pavel

Year of publication 2005
Type Article in Proceedings
Conference Sborních příspěvků 5. Pracovního setkání fyzikálních chemiků a elektrochemiků
MU Faculty or unit

Faculty of Science

Citation
Field Electrochemistry
Keywords benzene toluene dehalogenation adsorption CV aqueous solution
Description By means of DEMS technique has been studied the process of electrochemically mediated adsorptive oxidation of saturated solutions of benzene, chlorobenzene, fluorobenzene, toluene and o-dichlorobenzene on polycrystalline platinum electrode. All compounds undergoe to anodic oxidation yielding carbon oxide, detected by MS ion current of m/z 44. The results are presented as CV and MS/CV curves. Platinum Pt(111) and Pt(110) have been used as working electrodes in case studies of electro-sorption of chlorobenzene, fluorobenzene and bromobenzene from acid water solutions of different concentrations.
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