Intra-intermolecular criss-cross cycloadditions of nonsymmetrical allenylazines with fluorinated enone

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Title in English ntra-intermolecular criss-cross cycloadditions of nonsymmetrical allenylazines with fluorinated enone
Authors

MAN Stanislav NEČAS Marek BOUILLON Jean-Philippe PORTELLA Charles POTÁČEK Milan

Year of publication 2006
Type Article in Proceedings
Conference Chemické Listy
MU Faculty or unit

Faculty of Science

Citation
Field Organic chemistry
Keywords criss-cross; cycloaddition; fluorinated; enone; allenylazines;
Description Criss-cross cycloadditions are well known for a rather long time as a special case of [2+3], respectively 1,3-dipolar cycloadditions. Based on our knowledge of combined intra-intermolecular criss-cross cycloadditions of nonsymmetrical allenylazines with phenylisocyanate and alkynes, we studied this reaction with a new fluorinated dipolarophile (fluorinated enone).
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