Experimental determination of phase equilibria and reassessment of Ag-Pd system

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Authors	SOPOUŠEK Jiří ZEMANOVÁ Adéla VŘEŠŤÁL Jan BROŽ Pavel
Year of publication	2010
Type	Article in Periodical
Magazine / Source	Journal of Alloys and Compounds
MU Faculty or unit	Faculty of Science
Citation
Doi	http://dx.doi.org/10.1016/j.jallcom.2010.05.141
Field	Thermodynamics
Keywords	Silver; Palladium; Thermal analysis; Knudsen effusion method; CALPHAD
Description	The existing assessment of thermodynamic and phase equilibrium data in the Ag-Pd system was revised on the basis of calorimetric data for liquid Ag-Pd alloys published recently in the literature and on new determination of liquidus and solidus temperatures and activity data for Ag in liquid phase, using differential scanning calorimetry (DSC) coupled with Knudsen cell mass spectrometry (KC/MS). A substantially narrower liquid/fcc two-phase field in phase diagram as well as new non-ideal activity data were revealed.
Related projects:	Thermodynamic and Phase Diagram Studies of Systems for High Temperature Lead-Free Solders