PREPARATION OF NEW COORDINATION COMPOUNDS OF (1-AMINO-1-METHYL-ETHYL) PHOSPHONIC ACID WITH SOME d-METALS AND URANYL ION
| Autoři | |
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| Rok publikování | 2014 |
| Druh | Konferenční abstrakty |
| Fakulta / Pracoviště MU | |
| Citace | |
| Popis | Because of their different properties and structural varieties chemistry of phosphates is one of the central topics in material science for many years. Also related phosphonate materials are widely and rapidly studied and used in different fields and applications. They can be used as adsorbents, ionic exchangers, ionic conductors and in catalysis1 C bond in phosphonates makes us possible to diversify their structures, to introduce substituent groups with interesting properties or another coordination group that would allow us to use these compounds in crystal engineering. In this work new coordination compounds of early known 2 with Fe2+ , Fe3+ synthesized. Usual metals salts (nitrates, chlorides and sulfates) were used in a role of precursors. Reactions were carried out in the water and methanol media. Obtained compounds were studied by IR-spectroscopy, TG/DSC analysis and nitrogen adsorption BET analysis of specific surface. Crystal structures of crystalline samples were measured by mono-crystal X-ray diffraction analysis. etc. Possibility of existence of strong P– (1-amino-1-methyl-ethyl)phosphonic acid , Co2+ , Ni2+ , Cu2+ and UO2 were 2+ |
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