Supramolecular approach to detection of multicomponent anion mixtures by 1H NMR in aqueous environment
| Autoři | |
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| Rok publikování | 2015 |
| Druh | Další prezentace na konferencích |
| Citace | |
| Popis | Two bambusuril derivatives were applied in the detection of anions in aqueous mixtures. Bambusurils exhibits slow exchange on the NMR time scale upon the anion binding resulting in the unique and highly reproducible signals for different anion complexes. This allowed us to demonstrate qualitative detection of 12 and quantitative of 5 anions in 5% D2O - DMSO-d6 mixture and quantitative detection of I- and ClO4- in D2O on submicromolar level. |
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