Project information
Chalcogen organic compounds - synthesis, transformation and structure elucidation
- Project Identification
- GA203/01/1333
- Project Period
- 1/2001 - 1/2003
- Investor / Pogramme / Project type
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Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
The substantiality of this project is extension of new acknowledgments found by applicant research group in field of syntheses, transformations and structure elucidation of heterocycles containing nitrogen, sulfur, selenium and tellurium into molecule. F irst of all synthesis, transformation reactions and elucidation of bond conditions will be studied on some novel compounds containing trichalcapentalene skeleton. Furthermore studies of formation and reactivity of heterocycles containing S-S, S-Se, S-Te, Se-Se, Se-Te bonds, i. e. potential scavengers of free radicals. Formation of chalcogene-chalcogene bond will be realized by oxidative cyclization on 2-chalcogenoureidothiophenole and 2-chalcogenoureido-ethanthiole as model (chalcogen is S or Se). Along on compounds prepared by addition of chalcogenide anion on both cyano groups into dinitrile diaminomaleic acid and its derivatives with iunctionalized amino group (acyl-, thioacylamino, and chalcogenoureido groups). By an application of electrochemical
Publications
Total number of publications: 34
2008
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Unexpected Formation of Benzothiazoles in the Synthesis of New Heterocycles: Benzo-1,2,4-dithiazines
Synthesis, year: 2008, volume: 2008, edition: 8
2007
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Synthesis and reactions of methyl 2-[3-(2-phenylquinazolin-4-yl)thioureido]alkanoates
ARKIVOC, year: 2007, volume: 2007, edition: i
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Synthesis of New 1-Substituted-4-(2-phenylquinazolin-4-yl and 4-ylidene) Thiosemicarbazide
11th INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY, year: 2007
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Vibrational spectroscopic studies and ab initio calculations of 2-cyanophenylisocyanid dichloride
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, year: 2007, volume: 67, edition: 4
2006
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TRANSFORMATION OF 1,2-DITHIOLE-3-THIONES INTO 1,6,6alambda4-TRITHIAPENTALENES via REACTION WITH BROMOETHANONES
Collection of Czechoslovak Chemical Communications, year: 2006, volume: 71, edition: 5
2004
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SYNTHESIS OF 4,6-DISUBSTITUTED-2-(1H-INDOL-3-YL)-BENZOTHIAZOLES
Collection of Czechoslovak Chemical Communications, year: 2004, volume: 69, edition: 1
2003
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N-(2-Cyanophenyl)benzenecarboximidoyl Isothiocyanate - Efficient Educt for Domino-Syntheses of Heterocycles
The Tenth Blue Danube Symposium on Heterocyclic Chemistry, year: 2003
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Reaction in The Solid State. Isomerization of N-Acylselenoureas into N-Acylisoselenoureas
Proceedings of ECSOC-7, The Seventh International Electronic Conference on Synthetic Organic Chemistry, http://www.mdpi.org/ecsoc-7.htm, September 1-30, 2003. Editors: Julio A. Seijas, De-Chun Ji and Shu-Kun Lin. CD-ROM edition, year: 2003
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Syntéza dusíkatých heterocyklů multikomponentními domino reakcemi
Chemické listy, year: 2003, volume: 97, edition: 11
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Syntéza nového 4H-benzo[1,2,4]dithiazinového skeletu a studium jeho elektrochemického chování
CHEMICKÉ LISTY, year: 2003, volume: 97, edition: 8