The Reaction of P3N3Cl4(NH2)2 with HCl; The Crystal Structure of P3N3Cl5(NH2).

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Title in English	The Reaction of [P3N3Cl4(NH2)2] with [HN(POCl2)2]; the Crystal Structure of a Phosphazenium Salt [P3N3HCl4(NH2)2]+ [N(POCl2)2]-.
Authors	ALBERTI Milan BŘÍNEK Josef MAREK Jaromír TOUŽÍN Jiří
Year of publication	1997
Type	Article in Periodical
Magazine / Source	Zeitschrift für anorganische und allgemeine Chemie [Bd. 380 (1971) -]
MU Faculty or unit	Faculty of Science
Citation
Field	Inorganic chemistry
Keywords	preparation; crystal structure; molecular structure; vibrational spectra
Description	P3N3Cl5(NH2) in high purity and good yield can be obtained by the reaction of P3N3Cl4(NH2)2 with gaseous HCl in acetonitrile If diethylether or dichlormethane is used as a solvent, a salt-like compound [P3N3Cl4H(NH2)2+Cl- is formed as a microcrystalline product instead of P3N3Cl5(NH2). The crystal structure of P3N3Cl5(NH2)was determined by X-ray structure analysis. Vibrational spectra and thermic behavior of both P3N3Cl5(NH2)and [P3N3Cl4H(NH2)2+Cl- are also briefly discussed.
Related projects:	Structure and Bonding in the Compounds of Nitrogen,Phosphorus,Sulfur and Selenium and in the Complexes of Fe,Co,and Ni with N,P,S-Ligands